Cyclopentadienyl Cobalt Cyclooctatetraene
نویسندگان
چکیده
منابع مشابه
Bis-cyclooctatetraene tripalladium sandwich complexes.
We report synthesis and structural characterization of bis-cyclooctatetraene trinuclear palladium sandwich complexes. The non-planar cyclooctatetraene ligands flank an isosceles Pd3 triangle, which is supported by one equatorial ligand.
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für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...
متن کاملRole of bifurcation in the bond shifting of cyclooctatetraene
The present study of the cyclooctatetraene potential energy surface shows the presence of a bifurcation (valley ridge inflection point) in the intrinsic reaction coordinate path between the two transition states of D(8h) and D(4h) symmetries. This result is of capital importance for the correct understanding of the bond shifting and ring inversion processes in this compound.
متن کاملPentaarylfullerenes as noncoordinating cyclopentadienyl anions.
The first example of an early-transition-metal complex involving a pentaarylfullerene was prepared. Instead of half-sandwich complexes, solvent separated ion pairs were obtained in which the pentaarylfullerene moiety acts as noncoordinating cyclopentadienyl anion.
متن کاملTricarbonyl(η5-cyclopentadienyl)(trifluorohydroxyborato)tungsten.
The title compound, [W(C(5)H(5))(HOBF(3))(CO)(3)], has a four-legged piano-stool geometry which is typically found for C(5)H(5)W(CO)(3)X complexes. The HOBF(3)(-) anion is the hydrolysis product of BF(4)(-) and is coordinated via oxygen.
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1960
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.33.425